New controlled release systems produced by self-assembly of biopolymers and colloidal particles at fluid-fluid interfaces

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L van den Berg, T van Vliet, E van der Linden, MAJS van Boekel, F van de Velde, Physical properties giving the sensory perception of whey proteins/polysaccharide gels FOOD BIOPHYSICS 3 (2008) 198 ► Establishing relationships between physical and sensorial properties of semi-solid foods is essential to develop tailored products. Whey protein/polysaccharide mixed gels were used to model both natural and fabricated semi-solid foods. The presence of various polysaccharides modulated the microstructure and large deformation properties of the mixed gels. The gels exhibited a large spectrum of sensorial properties as evaluated by panellists in a quantitative descriptive analysis. Mouthfeel attributes that discriminated best between the gels were wateriness, crumbliness, and spreadability. Wateriness strongly correlated with the amount of exuded phase (serum) measured during uniaxial compression. Serum release may have a positive effect on, for instance, the juiciness of a product. Large deformation measurements showed that highly crumbly gels fracture readily via a free-running crack. Low serum release is a requirement for that. Low crumbly gels fracture slowly, often releasing a high amount of serum. Spreadability related to the occurrence of multiple microcracks during deformation as observed by confocal laser scanning microscopy, which resulted in a large number of pieces after oral processing. [hide] Scientific Board Andreas Bausch  TU Munich, Germany ► Peter Fischer  ETH Zurich, Switzerland ► Anne-Marie Hermansson  SIK, Sweden ► Martin Kroger  ETH Zurich, Germany/Switzerland ► Erik van der Linden  Wageningen UR, The Netherlands ► Niklas Loren  SIK, Sweden ► Leonard Sagis  Wageningen UR, The Netherlands ► Erich Windhab  ETH Zurich, Switzerland ► Klaas-Jan Zuidam  Unilever, The Netherlands ► Scientific Stuff Manuela Duxenneuner  ETH Zurich, Switzerland ► Sophia Fransson  SIK, Sweden ► Nam-Phuong Humblet-Hua  Wageningen UR, The Netherlands ► Joeska Husny  ETH Zurich, Australia/Switzerland ► Orit Peleg  ETH Zurich, Israel/Switzerland ► Cyrille Vezy  TU Munich, Germany ► Varvara Mitropoulos  ETH Zurich, Switzerland ► Associated Scientists
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networks SOFT MATTER 4 (2008) 2365 ► NP Humblet-Hua, LMC Sagis, E van der Linden, Effects of Flow on Hen Egg White Lysozyme (HEWL) Fibril Formation: Length Distribution, Flexibility, and Kinetics JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY 56 (2008) 11875 ► C Semmrich, RJ Larsen, AR Bausch, Nonlinear mechanics of entangled F-actin solutions SOFT MATTER 4 (2008) 1675 ► JK Jonasson, N Loren, P Olofsson, M Nyden, M Rudemo, A pixel-based likelihood framework for analysis of fluorescence recovery after photobleaching data JOURNAL OF MICROSCOPY-OXFORD 232 (2008) 260 ► LMC Sagis, Dynamics of controlled release systems based on water-in-water emulsions: A general theory JOURNAL OF CONTROLLED RELEASE 131 (2008) 5 ► LMC Sagis, Dynamics of Encapsulation and Controlled Release Systems Based on Water-in-Water Emulsions: Negligible Surface Rheology JOURNAL OF PHYSICAL CHEMISTRY B 112 (2008) 13503 ► N Muller-Fischer, P Tobler, M Dressler, P Fischer, EJ Windhab, Single bubble deformation and breakup in simple shear flow EXPERIMENTS IN FLUIDS 45 (2008) 917 ► P Fischer, H Wu, Morphological transitions in dilute solutions of sugar-based zwitterionic dimer betaine surfactants COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 326 (2008) 103 ► P Erni, P Fischer, V Herle, M Haug, EJ Windhab, Complex interfaces and their role in protein-stabilized soft materials CHEMPHYSCHEM 9 (2008) 1833 ► KM Schmoller, O Lieleg, AR Bausch, Cross-linking molecules modify composite actin networks independently PHYSICAL REVIEW LETTERS 101 (2008) 118102 ► E Del Gado, P Ilg, M Kroger, HC Ottinger, Nonaffine deformation of inherent structure as a static signature of cooperativity in supercooled liquids PHYSICAL REVIEW LETTERS 101 (2008) 095501 ► W Zhuang, E Kasemi, Y Ding, M Kroger, AD Schluter, JP Rabe, Self-folding of charged single dendronized polymers ADVANCED MATERIALS 20 (2008) 3204 ► O Lieleg, MMAE Claessens, Y Luan, AR Bausch, Transient binding and dissipation in cross-linked actin networks PHYSICAL REVIEW LETTERS 101 (2008) 108101 ► J Soulages, T Schweizera, DC Venerus, M Kroger, HC Ottinger, Lubricated cross-slot flow of a low density polyethylene melt JOURNAL OF NON-NEWTONIAN FLUID MECHANICS 154 (2008) 52 ► RD Egholm, P Fischer, K Feigl, EJ Windhab, R Kipka, P Szabo, Experimental and numerical analysis of droplet deformation in a complex flow generated by a rotor-stator device CHEMICAL ENGINEERING SCIENCE 63 (2008) 3526 ► L van den Berg, HJ Klok, T van Vliet, E van der Linden, MAJS van Boekel, F van de Velde, Quantification of a 3D structural evolution of food composites under large deformations using microrheology FOOD HYDROCOLLOIDS 22 (2008) 1574 ► MMAE Claessens, C Semmrich, L Ramos, AR Bausch, Helical twist controls the thickness of F-actin bundles PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 105 (2008) 8819 ► L van den Berg, AL Carolas, T van Vliet, E van der Linden, MAJS van Boekel, F van de Velde, Energy storage controls crumbly perception in whey proteins/polysaccharide mixed gels FOOD HYDROCOLLOIDS 22 (2008) 1404 ► IV Karlin, M Colangeli, M Kroger, Exact linear hydrodynamics from the Boltzmann equation PHYSICAL REVIEW LETTERS 100 (2008) 214503 ► JM Kim, DJ Keffer, M Kroger, BJ Edwards, Rheological and entanglement characteristics of linear-chain polyethylene liquids in planar Couette and planar elongational flows JOURNAL OF NON-NEWTONIAN FLUID MECHANICS 152 (2008) 168 ► V Herle, S Manneville, P Fischer, Ultrasound velocimetry in a shear-thickening wormlike micellar solution: Evidence for the coexistence of radial and vorticity shear bands EUROPEAN PHYSICAL JOURNAL E 26 (2008) 3 ► S Rammensee, U Slotta, T Scheibel, AR Bausch, Assembly mechanism of recombinant spider silk proteins PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 105 (2008) 6590 ► O Peleg, M Kroger, Y Rabin, Model of microphase separation in two-dimensional gels MACROMOLECULES 41 (2008) 3267 ► M Bathe, C Heussinger, MMAE Claessens, AR Bausch, E Frey, Cytoskeletal bundle mechanics BIOPHYSICAL JOURNAL 94 (2008) 2955 ► LMC Sagis, R de Ruiter, FJR Miranda, J de Ruiter, K Schroen, AC van Aelst, H Kieft, R Boom, E van der Linden, Polymer microcapsules with a fiber-reinforced nanocomposite shell LANGMUIR 24 (2008) 1608 ► M Kroger, A Ammar, F Chinesta, Consistent closure schemes for statistical models of anisotropic fluids JOURNAL OF NON-NEWTONIAN FLUID MECHANICS 149 (2008) 40 ► G Maurstad, YA Morch, AR Bausch, BT Stokke, Polyelectrolyte layer interpenetration and swelling of alginate-chitosan multilayers studied by dual wavelength reflection interference contrast microscopy CARBOHYDRATE POLYMERS 71 (2008) 672 ► M Kroger, Landmark paper index: Application to rheological (eta-) journals APPLIED RHEOLOGY 17 (2007) 348 ► M Kroger, Landmark paper index: Application to rehological (eta-)journals APPLIED RHEOLOGY 17 (2007) 66494 ► LMC Sagis, CG Boeriu, GE Frissen, HA Schols, PA Wierenga, Highly stable foams from block oligomers synthesized by enzymatic reactions LANGMUIR 24 (2008) 359 ► Y Luan, O Lieleg, B Wagner, AR Bausch, Micro- and macrorheological properties of isotropically cross-linked actin networks BIOPHYSICAL JOURNAL 94 (2008) 688 ► C Semmrich, T Storz, J Glaser, R Merkel, AR Bausch, K Kroy, Glass transition and rheological redundancy in F-actin solutions PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 104 (2007) 20199 ► M Kroger, O Peleg, Y Ding, Y Rabin, Formation of double helical and filamentous structures in models of physical and chemical gels SOFT MATTER 4 (2008) 18 ► N Duerr-Auster, J Kohlbrecher, T Zuercher, R Gunde, P Fischer, E Windhab, Microstructure and stability of a lamellar liquid crystalline and gel phase formed by a polyglycerol ester mixture in dilute aqueous solution LANGMUIR 23 (2007) 12827 ► KD Hermanson, MB Harasim, T Scheibel, AR Bausch, Permeability of silk microcapsules made by the interfacial adsorption of protein PHYSICAL CHEMISTRY CHEMICAL PHYSICS 9 (2007) 6442 ► MEJ Terpstra, AM Janssen, E van der Linden, Exploring imperfect squeezing flow measurements in a teflon geometry for semisolid foods JOURNAL OF FOOD SCIENCE 72 (2007) E492 ► P Erni, V Herle, EJ Windhab, P Fischer, Shape and interfacial viscoelastic response of emulsion droplets in shear flow Food Colloids: Self-Assembly and Material Science ROYAL SOCIETY OF CHEMISTRY SPECIAL PUBLICATIONS 302 (2007) 343 ► P Erni, EJ Windhab, R Gunde, M Graber, B Pfister, A Parker, P Fischer, Interfacial rheology of surface-active blopolymers: Acacia senegal gum versus hydrophobically modifed starch BIOMACROMOLECULES 8 (2007) 3458 ► P Fischer, P Erni, Emulsion drops in external flow fields - The role of liquid interfaces CURRENT OPINION IN COLLOID & INTERFACE SCIENCE 12 (2007) 196 ► AM Grannas, AR Bausch, KM Mahanna, Enhanced aqueous photochemical reaction rates after freezing JOURNAL OF PHYSICAL CHEMISTRY A 111 (2007) 11043 ► PA Neff, A Serr, 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neurofilament hydrogels EUROPEAN BIOPHYSICS JOURNAL WITH BIOPHYSICS LETTERS 36 (2007) 661 ► SG Bolder, LMC Sagis, P Venema, E van der Linden, Effect of stirring and seeding on whey protein fibril formation JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY 55 (2007) 5661 ► M Schonhoff, V Ball, AR Bausch, C Dejugnat, N Delorme, K Glinel, RV Klitzing, R Steitz, Hydration and internal properties of polyelectrolyte multilayers COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 303 (2007) 14 ► P Fischer, A Eugster, EJ Windhab, M Schuleit, Predictive stress tests to study the influence of processing procedures on long term stability of supersaturated pharmaceutical o/w creams INTERNATIONAL JOURNAL OF PHARMACEUTICS 339 (2007) 189 ► KD Hermanson, D Huemmerich, T Scheibel, AR Bausch, Engineered microcapsules fabricated from reconstituted spider silk ADVANCED MATERIALS 19 (2007) 1810 ► K Feigl, D Megias-Alguacil, P Fischer, EJ Windhab, Simulation and experiments of droplet deformation and orientation in simple shear flow with surfactants CHEMICAL ENGINEERING SCIENCE 62 (2007) 3242 ► C Mohrdieck, F Dalmas, E Arzt, R Tharmann, MMAE Claessens, AR Bausch, A Roth, E Sackmann, CHJ Schmitz, J Curtis, W Roos, S Schulz, K Uhrig, JP Spatz, Biomimetic models of the actin cytoskeleton SMALL 3 (2007) 1015 ► M Colangeli, IV Karlin, M Kroger, From hyperbolic regularization to exact hydrodynamics for linearized Grad's equations PHYSICAL REVIEW E 75 (2007) 051204 ► SG Bolder, AJ Vasbinder, LMC Sagis, E van der Linden, Heat-induced whey protein isolate fibrils: Conversion, hydrolysis, and disulphide bond formation INTERNATIONAL DAIRY JOURNAL 17 (2007) 846 ► MA Pollard, R Kelly, C Wahl, P Fischer, E Windhab, B Eder, R Amado, Investigation of equilibrium solubility of a carob galactomannan FOOD HYDROCOLLOIDS 21 (2007) 683 ► L van den Berg, T van Vliet, E van der Linden, MAJS van Boekel, F van de Velde, Breakdown properties and sensory perception of whey proteins/polysaccharide mixed gels as a function of microstructure FOOD HYDROCOLLOIDS 21 (2007) 961 ► O Peleg, M Kroger, I Hecht, Y Rabin, Filamentous networks in phase-separating two-dimensional gels EPL 77 (2007) 58007 ► SG Bolder, LMC Sagis, P Venema, E van der Linden, Thioflavin T and birefringence assays to determine the conversion of proteins into fibrils LANGMUIR 23 (2007) 4144 ► S Shanbhag, M Kroger, Primitive path networks generated by annealing and geometrical methods: Insights into differences MACROMOLECULES 40 (2007) 2897 ► PA Neff, BK Wunderlich, R von Klitzing, AR Bausch, Formation and dielectric properties of polyelectrolyte multilayers studied by a silicon-on-insulator based thin film resistor LANGMUIR 23 (2007) 4048 ► LMC Sagis, Nonequilibrium thermodynamic model of water-in-water emulsions JOURNAL OF PHYSICAL CHEMISTRY C 111 (2007) 3139 ► K Mohlin, N Loren, M Nyden, Water pores in alkyl ketene dimer (AKD) dispersions studied by NMR diffusometry and optical microscopy COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 297 (2007) 114 ► O Lieleg, MMAE Claessens, C Heussinger, E Frey, AR Bausch, Mechanics of bundled semiflexible polymer networks BIOPHYSICAL JOURNAL (2007Suppl.S) 139A ► M Bathe, MMAE Claessen, C Heussinger, AR Bausch, E Frey, F-actin bundle mechanical properties are sensitively mediated by actin-binding proteins and bundle dimensions BIOPHYSICAL JOURNAL (2007Suppl.S) 175A ► R Tharmann, MMAE Claessens, AR Bausch, Viscoelasticity of isotropically cross-linked actin networks PHYSICAL REVIEW LETTERS 98 (2007) 088103 ► LMC Sagis, Fluctuations of permeable interfaces in water-in-water emulsions PHYSICAL REVIEW LETTERS 98 (2007) 066105 ► R Nisslert, M Kvarnstrom, N Loren, M Nyden, M Rudemo, Identification of the three-dimensional gel microstructure from transmission electron micrographs JOURNAL OF MICROSCOPY-OXFORD 225 (2007) 10 ► J Brink, M Langton, M Stading, AM Hermansson, Simultaneous analysis of the structural and mechanical changes during large deformation of whey protein isolate/gelatin gels at the macro and micro levels FOOD HYDROCOLLOIDS 21 (2007) 409 ► L van den Berg, T van Vliet, E van der Linden, MAJS van Boekel, F van de Velde, Serum release: The hidden quality in fracturing composites FOOD HYDROCOLLOIDS 21 (2007) 420 ► C Lofgren, AM Hermansson, Synergistic rheological behaviour of mixed HM/LM pectin gels FOOD HYDROCOLLOIDS 21 (2007) 480 ►	login name password
Selected conferences (co-)organized by project members 8th World Congress on Computational Mechanics WCCM8 2008 30 June - 5 July 2007, Venice, Italy ► XVth International Workshop on Numerical Methods for non-Newtonian Flows 6-10 August 2007, Rhodes, Greece ► Structure Dynamics in Soft Condensed Matter (EUCHEM conference) 20-22 August 2007, Fiskebackskil, Sweden ►

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